郑军 特聘研究员 博士生导师
招生专业：制药工程 （博士/学硕/专硕）
E-mail: jz@ecust.edu.cn
课题组网站：郑军课题组 (x-mol.com)
通讯地址：上海市徐汇区梅陇路130号实验18楼631室；邮编：200237
个人简介：
2011年本科毕业于苏州大学材料与化学化工学部，并于2016年在上海有机化学研究所取得博士学位，师从游书力研究员。随后加入德国弗莱堡大学Bernhard Breit教授课题组开展博士后研究。2022年7月加入华东理工大学药学院开展独立研究。曾获上海市高层次人才引进计划 (2021)，德国洪堡奖学金 (2017)，中科院优秀博士论文(2017)，SABIC-CAS SCHOLARSHIP (2016) 和中国科学院院长优秀奖 (2016)。
研究方向：
课题组主要研究兴趣有不对称催化，自由基化学，合成方法学，天然产物合成以及新药研发。
成果及论文：
Independent Work:
Under cooking
Prior to ECUST:
13. Regio- and Diastereoselective Decarboxylative Allylation of N-Aryl α-Amino Acids by Dual Photoredox/Nickel Catalysis.
J. Zheng,‡ C. Nopper,‡ R. Bibi, A. Nikbakht, F. Bauer, B. Breit,* ACS Catal. 2022, 12, 5949−5960. (‡J.Z. and C.N. contributed equally to this work.)
12. Regio-, Diastereo-, and Enantioselective Decarboxylative Hydroaminoalkylation of Dienol Ethers Enabled by Dual Palladum/Photoredox Catalysis.
J. Zheng,* N. Tang, H. Xie, B. Breit,* Angew. Chem. Int. Ed. 2022, DOI: 10.1002/anie.202200105.
11. Dual Palladium/Photoredox-Catalyzed Enantioselective and Regioselective Decarboxylative Hydroaminoalkylation of Allenes.
J. Zheng, Ali Nikbakht, and Bernhard Breit,* ACS Catal. 2021, 11, 3343−3350.
10. Regiodivergent Hydroaminoalkylation of Alkynes and Allenes by a Combined Rhodium and Photoredox Catalytic System.
J. Zheng, B. Breit,* Angew. Chem. Int. Ed. 2019, 58, 3392-3397.
9. Asymmetric Synthesis of Spiropyrazolones by Rhodium-Catalyzed C(sp2)–H Functionalization/Annulation Reactions.
J. Zheng, S.-B. Wang, C. Zheng, S.-L. You,* Angew. Chem. Int. Ed. 2017, 56, 4540-4544. (Highlighted by Synfacts 2017, 13(6), 0609).
8. Synthesis and Application of Chiral Spiro Cp Ligands in RhodiumCatalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes.
J. Zheng, W.-J. Cui, C. Zheng, S.-L. You,* J. Am. Chem. Soc. 2016, 138, 5242-5245.
7. A DFT Study on Rh-Catalyzed Asymmetric Dearomatization of 2-Naphthols Initiated with C–H Activation: A Refined Reaction Mechanism and Origins of Multiple Selectivity.
C. Zheng, * J. Zheng, S.-L. You,* ACS Catal. 2016, 6 (1), 262-271.
6. Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp2)–H Functionalization/Annulation Reaction.
J. Zheng, S.-B. Wang, C. Zheng, S.-L. You,* J. Am. Chem. Soc. 2015, 137, 4880-4883. (Highlighted by Synfacts 2015, 11(7),0721)
5. Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes. J. Zheng, S.-L. You,* Angew. Chem. Int. Ed. 2014, 53, 13244-13247.
4. Palladium-Catalyzed Trisallylation of Azoles with Alkyne via sequential C(sp2)-H and C(sp3)-H Functionalization.
J. Zheng, F. Hosseini-Eshbala, Y.-X. Dong, B. Breit,* Chem. Commun. 2019, 55, 624-627.
3. Palladium-Catalyzed Direct C-H Allylation of Electron-Deficient Polyfluoroarenes with Alkynes.
J. Zheng, B. Breit,* Org. Lett. 2018, 20, 1866-1870.
2. Rhodium-catalyzed direct coupling of biaryl pyridine derivatives with internal alkynes.
J. Zheng, S.-L. You,* Chem. Commun. 2014, 50, 8204-8207.
1. Rhodium-Catalyzed Chemo-, Regio-, and Enantioselective Allylation of 2-Aminothiazoles with Terminal Allenes.
J. Zheng, B. Worl, B. Breit,* Eur. J. Org. Chem. 2019, 21, 5180-5182.
专利：
1. You, S.-L.; Zheng, J.; Cui, W.-J. Based on the spiro skeleton of cyclopentadiene compounds and their rhodium complex, preparation and application, Chinese Patent, 201610120414.7.